A New Approach to the Synthesis of Vicinal Iodoperoxyalkanes by the Reaction of Alkenes with Iodine and Hydroperoxides

Abstract A convenient procedure was developed for the synthesis of vicinal iodoperoxyalkanes by the reaction of alkenes with iodine and hydroperoxides. The best results were achieved with the use of excess iodine. The replacement of one iodine atom by hydroperoxides in vicinal diiodoalkanes was disc...

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Veröffentlicht in:Synthesis (Stuttgart) 2007-10, Vol.2007 (19), p.2979-2986
Hauptverfasser: Terent’ev, Alexander O., Krylov, Igor B., Borisov, Dmitry A., Nikishin, Gennady I.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract A convenient procedure was developed for the synthesis of vicinal iodoperoxyalkanes by the reaction of alkenes with iodine and hydroperoxides. The best results were achieved with the use of excess iodine. The replacement of one iodine atom by hydroperoxides in vicinal diiodoalkanes was discovered. A suggestion was made about the reaction mechanism.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2007-990776