Cobalt-Catalyzed Synthesis of Tertiary Azides from α,α-Disubstituted Olefins under Mild Conditions Using Commercially Available Reagents

Cobalt-Catalyzed Synthesis of Tertiary Azides from α,α-Disubstituted Olefins under Mild Conditions Using Commercially Available Reagents

Abstract The use of commercially available azide sources is presented for the cobalt-catalyzed hydroazidation reaction. α,α-Disubstituted olefins with a variety of functional groups were employed as substrates, providing tertiary azides in useful yields.

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Veröffentlicht in:Synthesis (Stuttgart) 2007-12, Vol.2007 (24), p.3839-3845
Hauptverfasser: Gaspar, Boris, Waser, Jérôme, Carreira, Erick M.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract The use of commercially available azide sources is presented for the cobalt-catalyzed hydroazidation reaction. α,α-Disubstituted olefins with a variety of functional groups were employed as substrates, providing tertiary azides in useful yields.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2007-1000817