Conjugate Reduction of α,β-Unsaturated Aldehydes with Rhodium(bis­oxazolinylphenyl) Catalysts

Conjugate Reduction of α,β-Unsaturated Aldehydes with Rhodium(bis­oxazolinylphenyl) Catalysts

ABSTRACT α,β-Unsaturated aldehydes were selectively reduced using rhodium(bisoxazolinylphenyl) complexes to give exclusive 1,4-selectivity in the combination of alkoxyhydrosilanes.

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Veröffentlicht in:Synlett 2006-12, Vol.2006 (19), p.3343-3345
Hauptverfasser: Kanazawa, Yoshinori, Nishiyama, Hisao
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT α,β-Unsaturated aldehydes were selectively reduced using rhodium(bisoxazolinylphenyl) complexes to give exclusive 1,4-selectivity in the combination of alkoxyhydrosilanes.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2006-951551