Electrochemical Cyclization of Dimethyl Aminomalonates

Electrochemical Cyclization of Dimethyl Aminomalonates

Abstract Dimethyl aminomalonates were electrochemically oxidized in methanol to afford the corresponding cyclization products through the formation of carbon-carbon bonds. Optimum yields were obtained when NaCN was utilized as the supporting electrolyte at room temperature. Presumably, the electroox...

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Veröffentlicht in:Synlett 2006-07, Vol.2006 (11), p.1753-1755
Hauptverfasser: Okimoto, Mitsuhiro, Yoshida, Takashi, Hoshi, Masayuki, Hattori, Kazuyuki, Komata, Masashi, Numata, Kaori, Tomozawa, Kenta
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Sprache:eng
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Zusammenfassung:Abstract Dimethyl aminomalonates were electrochemically oxidized in methanol to afford the corresponding cyclization products through the formation of carbon-carbon bonds. Optimum yields were obtained when NaCN was utilized as the supporting electrolyte at room temperature. Presumably, the electrooxidation involves a two-electron oxidation process.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2006-944205