Towards Reaction Selectivities of Imines and Aziridines

Towards Reaction Selectivities of Imines and Aziridines

Abstract Several simple and convenient transformations of imines and aziridines under mild conditions have been developed, rendering access to several kinds of β-amino derivatives, α-amino nitriles and phosphonates, aziridines, and conjugated dienes from imines and aziridines under neutral and metal...

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Veröffentlicht in:Synlett 2006-02, Vol.2006 (2), p.181-193
Hauptverfasser: Hou, Xue Long, Wu, Jie, Fan, Ren Hua, Ding, Chang Hua, Luo, Zhi Bin, Dai, Li Xin
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Sprache:eng
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Zusammenfassung:Abstract Several simple and convenient transformations of imines and aziridines under mild conditions have been developed, rendering access to several kinds of β-amino derivatives, α-amino nitriles and phosphonates, aziridines, and conjugated dienes from imines and aziridines under neutral and metal-free conditions very conveniently. High stereoselectivities are realized in most reactions based upon mechanistic considerations.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2006-926220