The Ever-Challenging Quassinoids
Abstract The evolution of a synthetic approach to the challenging targets quassinoids is described. 1 Introduction 2 The Diels-Alder Reaction as a Key Feature 2.1 Intermolecular Diels-Alder 2.2 Intramolecular Diels-Alder 2.3 Unsuccessful Diels-Alder Cycloadditions 3 The Diene-Transmissive Approach t...
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| Veröffentlicht in: | Synlett 2006-01, Vol.2006 (1), p.0023-0032 |
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| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
The evolution of a synthetic approach to the challenging targets quassinoids is described.
1 Introduction
2 The Diels-Alder Reaction as a Key Feature
2.1 Intermolecular Diels-Alder
2.2 Intramolecular Diels-Alder
2.3 Unsuccessful Diels-Alder Cycloadditions
3 The Diene-Transmissive Approach to Quassinoids
3.1 Without the C10 Methyl Group
3.2 With the C10 Methyl Group
4 A Successful Sequence
5 Conclusion and Outlook |
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| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-2005-921930 |