Regio- and Enantioselective Ring-Opening of Epoxides with HMDST: A Straightforward Access to 1,2-Mercaptoalcohols

Regio- and Enantioselective Ring-Opening of Epoxides with HMDST: A Straightforward Access to 1,2-Mercaptoalcohols

Abstract TBAF-catalyzed reaction of a range of substituted ­epoxides with hexamethyldisilathiane smoothly affords a direct and simple access to β-mercaptoalcohols in a highly regio- and stereoselective way.

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Veröffentlicht in:Synlett 2005-12, Vol.2005 (20), p.3063-3066
Hauptverfasser: Degl’Innocenti, Alessandro, Capperucci, Antonella, Cerreti, Arianna, Pollicino, Salvatore, Scapecchi, Serena, Malesci, Irene, Castagnoli, Giulio
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Sprache:eng
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Zusammenfassung:Abstract TBAF-catalyzed reaction of a range of substituted ­epoxides with hexamethyldisilathiane smoothly affords a direct and simple access to β-mercaptoalcohols in a highly regio- and stereoselective way.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2005-921922