A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyl­dimethylsilyl (TBDMS) Ethers with NBS in Water

A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyl­dimethylsilyl (TBDMS) Ethers with NBS in Water

ABSTRACT Treatment of TBDMS ethers with NBS in the presence of β-cyclodextrin in water results, for the first time, in the cleavage of the silicon-oxygen bond, carbonyl compounds are obtained upon oxidation.

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Veröffentlicht in:Synthesis (Stuttgart) 2005-04, Vol.2005 (5), p.714-716
Hauptverfasser: Reddy, M. Somi, Narender, M., Nageswar, Y. V., Rao, K. Rama
Format: Artikel
Sprache:eng
Schlagworte:
short paper
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Zusammenfassung:ABSTRACT Treatment of TBDMS ethers with NBS in the presence of β-cyclodextrin in water results, for the first time, in the cleavage of the silicon-oxygen bond, carbonyl compounds are obtained upon oxidation.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2005-861808