Carbon-Carbon Bond Formation by Cyclization of Dienes Using Phosphorus-Centered Radicals in Water

Carbon-Carbon Bond Formation by Cyclization of Dienes Using Phosphorus-Centered Radicals in Water

Abstract An efficient and mild methodology for preparing carbocyclic and heterocyclic compounds with phosphorus functionality by radical cyclization of dienes in water without using organic co-solvents has been developed. The reaction affords environmentally benign reaction conditions.

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Veröffentlicht in:Synlett 2005-01, Vol.2005 (1), p.59-62
Hauptverfasser: Cho, Dae Hyan, Jang, Doo Ok
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract An efficient and mild methodology for preparing carbocyclic and heterocyclic compounds with phosphorus functionality by radical cyclization of dienes in water without using organic co-solvents has been developed. The reaction affords environmentally benign reaction conditions.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-836041