Iridium Complex-Catalyzed Intramolecular Ene-Type Reaction of 1,6-Enynes Accelerated in Ionic Liquid

Abstract Iridium complex catalyzes an intramolecular ene-type reaction of 1,6-enynes to give cyclic 1,4-dienes. The reaction proceeds more efficiently in an imidazolium salt than in toluene and the ionic liquid can be reused.

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Veröffentlicht in:Synlett 2004-12, Vol.2004 (15), p.2812-2814
Hauptverfasser: Shibata, Takanori, Yamasaki, Mitsunori, Kadowaki, Sho, Takagi, Kentaro
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract Iridium complex catalyzes an intramolecular ene-type reaction of 1,6-enynes to give cyclic 1,4-dienes. The reaction proceeds more efficiently in an imidazolium salt than in toluene and the ionic liquid can be reused.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-835631