Diels-Alder Reactions of Substituted Cyclohexa-2,4-dienones with Alkenes and Alkynes

Abstract Substituted cyclohexa-2,4-dienones, generated in situ by pyrolysis of the appropriate dimer, participated in Diels-Alder reactions with various dienophiles to afford bicyclo[2.2.2]octenone and bicyclo[2.2.2]octadienone derivatives in high yields.

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Veröffentlicht in:Synlett 2004-11, Vol.2004 (14), p.2566-2569
Hauptverfasser: Gabrilidis, Dimitris, Kalogiros, Christos, Hadjiarapoglou, Lazaros P.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract Substituted cyclohexa-2,4-dienones, generated in situ by pyrolysis of the appropriate dimer, participated in Diels-Alder reactions with various dienophiles to afford bicyclo[2.2.2]octenone and bicyclo[2.2.2]octadienone derivatives in high yields.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-834798