Opening of N-Tosyl Aziridines with Nucleophiles Catalyzed by Phosphomolybdic Acid Supported on Silica Gel
Abstract An environmentally benign H 3 PMo 12 O 40 -SiO 2 -catalyzed regioselective opening of activated aziridines with alcohols, azide, cyanide and bromide, at ambient temperature to afford the corresponding β-amino derivatives in good yields is described.
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| Veröffentlicht in: | Synlett 2004-08, Vol.2004 (10), p.1719-1722 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
An environmentally benign H
3
PMo
12
O
40
-SiO
2
-catalyzed regioselective opening of activated aziridines with alcohols, azide, cyanide and bromide, at ambient temperature to afford the corresponding β-amino derivatives in good yields is described. |
|---|---|
| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-2004-829574 |