Iridium Nanoparticles Prepared in Ionic Liquids: An Efficient Catalytic System for the Hydrogenation of Ketones
Abstract Ir(0) nanoparticles with 2.3 ± 0.4 nm in diameter prepared by simple reduction of [Ir(cod)Cl] 2 in 1-N-butyl-3-methylimidazolium hexafluorophosphate ionic liquid constitute a simple, efficient and recyclable catalytic system for the solventless or biphasic hydrogenation of ketones under mil...
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| Veröffentlicht in: | Synlett 2004-07, Vol.2004 (9), p.1525-1528 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
Ir(0) nanoparticles with 2.3 ± 0.4 nm in diameter prepared by simple reduction of [Ir(cod)Cl]
2
in 1-N-butyl-3-methylimidazolium hexafluorophosphate ionic liquid constitute a simple, efficient and recyclable catalytic system for the solventless or biphasic hydrogenation of ketones under mild reaction conditions. |
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| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-2004-829061 |