A Highly Effective Diels-Alder Approach to cis-Clerodane Natural Products: First Total Synthesis of Solidago Alcohol

A Highly Effective Diels-Alder Approach to cis-Clerodane Natural Products: First Total Synthesis of Solidago Alcohol

ABSTRACT The first total synthesis of solidago alcohol (8) has been achieved in racemic form. The synthetic endeavor takes advantage of a facile and highly face-selective Diels-Alder cycloaddition reaction of cross-conjugated β-keto ester 3, readily accessible from 3-ethoxy-2-cyclohexenone, and TRAN...

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Veröffentlicht in:Synthesis (Stuttgart) 2004-02, Vol.2004 (2), p.271-275
Hauptverfasser: Ly, Tai Wei, Liao, Jyh-Hsiung, Shia, Kak-Shan, Liu, Hsing-Jang
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT The first total synthesis of solidago alcohol (8) has been achieved in racemic form. The synthetic endeavor takes advantage of a facile and highly face-selective Diels-Alder cycloaddition reaction of cross-conjugated β-keto ester 3, readily accessible from 3-ethoxy-2-cyclohexenone, and TRANS-piperylene.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2004-815916