Organophosphorus Compounds, Part 168; 1,3-Dipolar Cycloaddition Reactions of 1,3,5-Triphosphinines with Nitrile Oxides

Organophosphorus Compounds, Part 168; 1,3-Dipolar Cycloaddition Reactions of 1,3,5-Triphosphinines with Nitrile Oxides

ABSTRACT Phenylnitrile oxide as well as mesitylnitrile oxide underwent 1,3-dipolar cycloaddition reactions with the 1,3,5-triphosphinines 2 under mild conditions to furnish the condensed heterocyclic compounds 9 and 11, respectively. Oxadiphospholes 14 were accessible by fragmentation reactions of 1...

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Veröffentlicht in:Synthesis (Stuttgart) 2004-02, Vol.2004 (2), p.241-248
Hauptverfasser: Weidner, Steffen, Renner, Jens, Bergsträßer, Uwe, Regitz, Manfred, Heydt, Heinrich
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT Phenylnitrile oxide as well as mesitylnitrile oxide underwent 1,3-dipolar cycloaddition reactions with the 1,3,5-triphosphinines 2 under mild conditions to furnish the condensed heterocyclic compounds 9 and 11, respectively. Oxadiphospholes 14 were accessible by fragmentation reactions of 11.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2004-44384