Synthesis of Vinyl Sulfonamides Using the Horner Reaction

Synthesis of Vinyl Sulfonamides Using the Horner Reaction

ABSTRACT A series of vinyl sulfonamides was synthesized using the Horner reaction of aldehydes and diphenylphosphorylmethanesulfonamide. The sulfonamide reagent was easily prepared and can be stored indefinitely. The TRANS orientation about the double bond of the vinyl sulfonamides was the only isom...

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Veröffentlicht in:Synthesis (Stuttgart) 2003, Vol.2003 (15), p.2321-2324
Hauptverfasser: Reuter, Deborah C., McIntosh, Joel E., Guinn, Ashley C., Madera, Ann Marie
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT A series of vinyl sulfonamides was synthesized using the Horner reaction of aldehydes and diphenylphosphorylmethanesulfonamide. The sulfonamide reagent was easily prepared and can be stored indefinitely. The TRANS orientation about the double bond of the vinyl sulfonamides was the only isomer observed.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2003-41059