Synthesis of Paramagnetic Carbo- and Heterocycles

Synthesis of Paramagnetic Carbo- and Heterocycles

ABSTRACT Starting from paramagnetic β-bromo-α,β-unsaturated aldehyde 1, β-bromo-α,β-unsaturated nitrile 2 and diene 3 heterocycles 4-10 and carbocycles 12-14, 16, and 17 were synthesized with simple procedures in the presence of a nitroxide moiety. A complex-forming paramagnetic phenanthroline 19 is...

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Veröffentlicht in:Synthesis (Stuttgart) 2003, Vol.2003 (9), p.1361-1366
Hauptverfasser: Kulcsár, Győző, Kálai, Tamás, Jekő, József, Hideg, Kálmán
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT Starting from paramagnetic β-bromo-α,β-unsaturated aldehyde 1, β-bromo-α,β-unsaturated nitrile 2 and diene 3 heterocycles 4-10 and carbocycles 12-14, 16, and 17 were synthesized with simple procedures in the presence of a nitroxide moiety. A complex-forming paramagnetic phenanthroline 19 is also described.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2003-40206