Metallo-Enzyme Model in Pure Water: Cyclodextrin-Lanthanide Tris(perfluoroalkanesulfonyl)methide and Bis(perfluoroalkanesulfonyl)amide Complexes

Metallo-Enzyme Model in Pure Water: Cyclodextrin-Lanthanide Tris(perfluoroalkanesulfonyl)methide and Bis(perfluoroalkanesulfonyl)amide Complexes

Abstract Inclusion complexes of cyclodextrin/cyclodextrin co­polymer and lanthanide tris(perfluorobutanesulfonyl)methide/bis(perfluorobutanesulfonyl)amide, namely metallo-enzyme mo­del, are efficient and recyclable super Lewis acid catalysts, which can promote Diels-Alder and Mukaiyama-aldol reactio...

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Veröffentlicht in:Synlett 2002, Vol.2002 (10), p.1613-1616
Hauptverfasser: Nishikido, Joji, Nanbo, Masayuki, Yoshida, Akihiro, Nakajima, Hitoshi, Matsumoto, Yousuke, Mikami, Koichi
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Sprache:eng
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Zusammenfassung:Abstract Inclusion complexes of cyclodextrin/cyclodextrin co­polymer and lanthanide tris(perfluorobutanesulfonyl)methide/bis(perfluorobutanesulfonyl)amide, namely metallo-enzyme mo­del, are efficient and recyclable super Lewis acid catalysts, which can promote Diels-Alder and Mukaiyama-aldol reactions in pure water.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2002-34234