Diels-Alder Reactions of Silyl-Substituted Masked o-Benzoquinones: Expedient Access to Alkenylsilanes

Diels-Alder Reactions of Silyl-Substituted Masked o-Benzoquinones: Expedient Access to Alkenylsilanes

Abstract A one-pot synthesis of several silyl bicyclic and oxatricyclic alkenes by inter- and intramolecular Diels-Alder reactions of 4-trimethylsilyl substituted masked O-benzoquinones derived from the corresponding 2-methoxyphenols is described.

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Veröffentlicht in:Synlett 2002, Vol.2002 (9), p.1520-1522
Hauptverfasser: Lai, Chien-Hsun, Lin, Po-Yin, Peddinti, Rama Krishna, Liao, Chun-Chen
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract A one-pot synthesis of several silyl bicyclic and oxatricyclic alkenes by inter- and intramolecular Diels-Alder reactions of 4-trimethylsilyl substituted masked O-benzoquinones derived from the corresponding 2-methoxyphenols is described.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2002-33503