Organolithium-Induced Synthesis of Unsaturated Diols from Epoxides of Dihydrofurans and Dihydropyrans

Organolithium-Induced Synthesis of Unsaturated Diols from Epoxides of Dihydrofurans and Dihydropyrans

Abstract Dihydrofuran and dihydropyran epoxides undergo a stereospecific­ alkylative double ring-opening with organolithiums to provide a new route to substituted alkenediols.

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Veröffentlicht in:Synthesis (Stuttgart) 2002, Vol.2002 (10), p.1445-1453
Hauptverfasser: Hodgson, David M., Stent, Matthew A., Wilson, Francis X.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract Dihydrofuran and dihydropyran epoxides undergo a stereospecific­ alkylative double ring-opening with organolithiums to provide a new route to substituted alkenediols.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2002-33112