Tandem Oxidation Processes: The Direct Conversion of Activated Alcohols into Oximes; Synthesis of Citaldoxime

Tandem Oxidation Processes: The Direct Conversion of Activated Alcohols into Oximes; Synthesis of Citaldoxime

Abstract The direct conversion of primary alcohols into oximes is reported using manganese dioxide and alkoxylamines/hydroxyl­amine as their hydrochloride salts or supported on Amberlyst 15. This transformation has been applied to a range of benzylic, allylic and propargylic alcohols and utilised to...

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Veröffentlicht in:Synlett 2002, Vol.2002 (8), p.1287-1290
Hauptverfasser: Kanno, Hisashi, Taylor, Richard J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract The direct conversion of primary alcohols into oximes is reported using manganese dioxide and alkoxylamines/hydroxyl­amine as their hydrochloride salts or supported on Amberlyst 15. This transformation has been applied to a range of benzylic, allylic and propargylic alcohols and utilised to prepare the natural product citaldoxime.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2002-32949