Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems: Valuable Vinylogous Donor Substrates in Synthesis
Abstract Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be en...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2017-06, Vol.49 (11), p.2297-2336 |
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| container_title | Synthesis (Stuttgart) |
| container_volume | 49 |
| creator | Battistini, Lucia Curti, Claudio Rassu, Gloria Sartori, Andrea Zanardi, Franca |
| description | Abstract
Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.
1 Introduction
2 Alkylidene Oxindoles
3 Alkylidene Pyrazolinones
4 Alkylidene Furanones
5 Alkylidene Azlactones
6 Cycloalkylidene Carbonyl Compounds
7 Alkylidene Indenones
8 Cycloalkylidene Malononitriles
9 Conclusion |
| doi_str_mv | 10.1055/s-0036-1589487 |
| format | Article |
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Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.
1 Introduction
2 Alkylidene Oxindoles
3 Alkylidene Pyrazolinones
4 Alkylidene Furanones
5 Alkylidene Azlactones
6 Cycloalkylidene Carbonyl Compounds
7 Alkylidene Indenones
8 Cycloalkylidene Malononitriles
9 Conclusion</description><identifier>ISSN: 0039-7881</identifier><identifier>EISSN: 1437-210X</identifier><identifier>DOI: 10.1055/s-0036-1589487</identifier><language>eng</language><publisher>Stuttgart · New York: Georg Thieme Verlag</publisher><subject>review</subject><ispartof>Synthesis (Stuttgart), 2017-06, Vol.49 (11), p.2297-2336</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c277t-6623764b37128423a40c02be117cc36d77d32ea84c3d22b8fdcf83b050a40e193</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1589487.pdf$$EPDF$$P50$$Gthieme$$H</linktopdf><linktohtml>$$Uhttps://www.thieme-connect.de/products/ejournals/html/10.1055/s-0036-1589487$$EHTML$$P50$$Gthieme$$H</linktohtml><link.rule.ids>314,780,784,3017,3018,27924,27925,54559,54560</link.rule.ids></links><search><creatorcontrib>Battistini, Lucia</creatorcontrib><creatorcontrib>Curti, Claudio</creatorcontrib><creatorcontrib>Rassu, Gloria</creatorcontrib><creatorcontrib>Sartori, Andrea</creatorcontrib><creatorcontrib>Zanardi, Franca</creatorcontrib><title>Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems: Valuable Vinylogous Donor Substrates in Synthesis</title><title>Synthesis (Stuttgart)</title><addtitle>Synthesis</addtitle><description>Abstract
Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.
1 Introduction
2 Alkylidene Oxindoles
3 Alkylidene Pyrazolinones
4 Alkylidene Furanones
5 Alkylidene Azlactones
6 Cycloalkylidene Carbonyl Compounds
7 Alkylidene Indenones
8 Cycloalkylidene Malononitriles
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Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.
1 Introduction
2 Alkylidene Oxindoles
3 Alkylidene Pyrazolinones
4 Alkylidene Furanones
5 Alkylidene Azlactones
6 Cycloalkylidene Carbonyl Compounds
7 Alkylidene Indenones
8 Cycloalkylidene Malononitriles
9 Conclusion</abstract><cop>Stuttgart · New York</cop><pub>Georg Thieme Verlag</pub><doi>10.1055/s-0036-1589487</doi><tpages>40</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0039-7881 |
| ispartof | Synthesis (Stuttgart), 2017-06, Vol.49 (11), p.2297-2336 |
| issn | 0039-7881 1437-210X |
| language | eng |
| recordid | cdi_crossref_primary_10_1055_s_0036_1589487 |
| source | Thieme Connect Journals |
| subjects | review |
| title | Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems: Valuable Vinylogous Donor Substrates in Synthesis |
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