Palladium-Catalyzed Nitration of Arenes by 1,2,3-Triazole-Directed C–H Activation
Abstract An efficient palladium-catalyzed regioselective nitration of 1,4-disubstituted 1,2,3-triazoles has been described with good functional group compatibility, using Pd(OAc) 2 as the catalyst and NaNO 2 as the nitration source, leading to the synthesis of 1,2,3-triazoles containing nitro groups...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2016-07, Vol.48 (13), p.2105-2111 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
An efficient palladium-catalyzed regioselective nitration of 1,4-disubstituted 1,2,3-triazoles has been described with good functional group compatibility, using Pd(OAc)
2
as the catalyst and NaNO
2
as the nitration source, leading to the synthesis of 1,2,3-triazoles containing nitro groups in good to excellent yields. |
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| ISSN: | 0039-7881 1437-210X |
| DOI: | 10.1055/s-0035-1561951 |