Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P4S10)

Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P4S10)

Abstract The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et 3 N–P 2 S 5 ) was elaborated by utilizing DFT calc...

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Veröffentlicht in:Synthesis (Stuttgart) 2016-06, Vol.48 (20), p.3618-3624
Hauptverfasser: Turkoglu, Gulsen, Cinar, M. Emin, Ozturk, Turan
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et 3 N–P 2 S 5 ) was elaborated by utilizing DFT calculations.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0035-1561673