An Unsymmetrical Iron Catalyst for the Asymmetric Transfer Hydrogenation of Ketones
Abstract A new iron(II)(Ph 2 P–NH–N–PCy 2 ) complex with a dicyclohexylphosphino group trans to the NH group was found to catalyze the asymmetric transfer hydrogenation of a variety of ketones with high enantioselectivity.
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Veröffentlicht in: | Synthesis (Stuttgart) 2015-06, Vol.47 (12), p.1775-1779 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Abstract
A new iron(II)(Ph
2
P–NH–N–PCy
2
) complex with a dicyclohexylphosphino group
trans
to the NH group was found to catalyze the asymmetric transfer hydrogenation of a variety of ketones with high enantioselectivity. |
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ISSN: | 0039-7881 1437-210X |
DOI: | 10.1055/s-0034-1380147 |