Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents
Abstract Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dual-purpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acid...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2022-02, Vol.54 (3), p.754-762 |
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| container_title | Synthesis (Stuttgart) |
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| creator | Chen, Jyun-Siao Huang, Po-Hsun Hsieh, Ya-Chi Liu, Jen-Wei Hsu, Hsiao-Lin Zhang, Kai-Min Wu, Ren-Tsung Chang, Ting-Shuo Liu, Yu-Hao Wu, Hsin-Ru Luo, Shun-Yuan |
| description | Abstract
Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dual-purpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acidic or basic conditions. Herein, a detailed study on protection of various substrates and new methodological investigations is described. |
| doi_str_mv | 10.1055/a-1654-2211 |
| format | Article |
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Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dual-purpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acidic or basic conditions. Herein, a detailed study on protection of various substrates and new methodological investigations is described.</description><issn>0039-7881</issn><issn>1437-210X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNptj81Kw0AURgdRMFZXvkDWyui9M5lkshKp9QeKFqngbpgkN21KmpSZidC3N6UuXX2bw8c5jF0j3CEodW85pirhQiCesAgTmXGB8H3KIgCZ80xrPGcX3m8AIBMyj9jD0jVbCut965t238YzH8j52Pr4vf-hNn4abMsXg9v1nuKF6wOVoelW8SfZFXXBX7Kz2raerv52wr6eZ8vpK59_vLxNH-e8FCINvJCka6WULpMqpbwQNMolREonhaYS6worqFIQIJXVZYGikFDnaSoAk1xmcsJuj7-l6713VJvdKG7d3iCYQ7ux5tBuDu0jfXOkw7qhLZlNP7hu1PsX_gWyjFkZ</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Chen, Jyun-Siao</creator><creator>Huang, Po-Hsun</creator><creator>Hsieh, Ya-Chi</creator><creator>Liu, Jen-Wei</creator><creator>Hsu, Hsiao-Lin</creator><creator>Zhang, Kai-Min</creator><creator>Wu, Ren-Tsung</creator><creator>Chang, Ting-Shuo</creator><creator>Liu, Yu-Hao</creator><creator>Wu, Hsin-Ru</creator><creator>Luo, Shun-Yuan</creator><general>Georg Thieme Verlag KG</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220201</creationdate><title>Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents</title><author>Chen, Jyun-Siao ; Huang, Po-Hsun ; Hsieh, Ya-Chi ; Liu, Jen-Wei ; Hsu, Hsiao-Lin ; Zhang, Kai-Min ; Wu, Ren-Tsung ; Chang, Ting-Shuo ; Liu, Yu-Hao ; Wu, Hsin-Ru ; Luo, Shun-Yuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-b3e8f5558c4d6e9b2e1434ee584b8ec1fd1d0d602035a8cb12b30f96620149373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Jyun-Siao</creatorcontrib><creatorcontrib>Huang, Po-Hsun</creatorcontrib><creatorcontrib>Hsieh, Ya-Chi</creatorcontrib><creatorcontrib>Liu, Jen-Wei</creatorcontrib><creatorcontrib>Hsu, Hsiao-Lin</creatorcontrib><creatorcontrib>Zhang, Kai-Min</creatorcontrib><creatorcontrib>Wu, Ren-Tsung</creatorcontrib><creatorcontrib>Chang, Ting-Shuo</creatorcontrib><creatorcontrib>Liu, Yu-Hao</creatorcontrib><creatorcontrib>Wu, Hsin-Ru</creatorcontrib><creatorcontrib>Luo, Shun-Yuan</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis (Stuttgart)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Jyun-Siao</au><au>Huang, Po-Hsun</au><au>Hsieh, Ya-Chi</au><au>Liu, Jen-Wei</au><au>Hsu, Hsiao-Lin</au><au>Zhang, Kai-Min</au><au>Wu, Ren-Tsung</au><au>Chang, Ting-Shuo</au><au>Liu, Yu-Hao</au><au>Wu, Hsin-Ru</au><au>Luo, Shun-Yuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents</atitle><jtitle>Synthesis (Stuttgart)</jtitle><addtitle>Synthesis</addtitle><date>2022-02-01</date><risdate>2022</risdate><volume>54</volume><issue>3</issue><spage>754</spage><epage>762</epage><pages>754-762</pages><issn>0039-7881</issn><eissn>1437-210X</eissn><abstract>Abstract
Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dual-purpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acidic or basic conditions. Herein, a detailed study on protection of various substrates and new methodological investigations is described.</abstract><cop>Rüdigerstraße 14, 70469 Stuttgart, Germany</cop><pub>Georg Thieme Verlag KG</pub><doi>10.1055/a-1654-2211</doi><tpages>9</tpages></addata></record> |
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| title | Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents |
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