The influence of particle size and residual charge on electrostatic interactions between charged colloidal particles at an oil-water interface

Electrostatic repulsive interaction forces between charged spherical colloidal particles at an oil-water interface are numerically studied by solving the standard three-dimensional Poisson-Nernst-Planck model. We directly compute the electrostatic force on a finite-size spherical particle and our results are applicable to all inter-particle distances without distinguishing short ranges and long ranges. The model successfully captures the scaling relationship of the force and the separation distance ( d ) between two charged particles at both short ranges (exponential dependence) and long ranges (∼ d −4 ). The model also bridges these two ranges and provides quantitative information in the middle range. In addition, by assuming that there is a small residual electric charge at the particle-oil interface, the standard model is capable of quantitatively predicting the repulsive particle-particle interaction force over a large range of the separation distance between two particles. The favorable agreement between experiments and theoretical predictions also leads one to conclude that the standard model adequately describes the particle-particle interactions trapped at the oil-water interface. By accounting for residual charges on the particle-oil interface and particle size, the standard electrokinetic model can adequately predict particle-particle electrostatic interactions.