Formation of ethyl- and hydrido-iridium(III) complexes from the reaction of hydrated iridium(III) chloride with a pyridine-containing tetra-azamacrocycle in aqueous ethanolic solution. Crystal structure of trans-[IrCl(Et)L1][PF6] {L1=3,7,11-trimethyl-3,7,11,17-tetra-aza-bicyclo[11.3.1]heptadeca-1(17),13,15-triene}