A unique six-membered chelated iridium complex

A unique six-membered chelated iridium complex

The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl(3).nH(2)O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2008-01 (31), p.4095
Hauptverfasser: Ammermann, Sven, Daniliuc, Constantin, Jones, Peter G, du Mont, Wolf-Walther, Kowalsky, Wolfgang, Johannes, Hans-Hermann
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container_issue 31
container_start_page 4095
container_title Dalton transactions : an international journal of inorganic chemistry
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creator Ammermann, Sven
Daniliuc, Constantin
Jones, Peter G
du Mont, Wolf-Walther
Kowalsky, Wolfgang
Johannes, Hans-Hermann
description The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl(3).nH(2)O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.
doi_str_mv 10.1039/b807735p
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title A unique six-membered chelated iridium complex
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