A unique six-membered chelated iridium complex

The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl(3).nH(2)O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.

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Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2008-01 (31), p.4095
Hauptverfasser:	Ammermann, Sven, Daniliuc, Constantin, Jones, Peter G, du Mont, Wolf-Walther, Kowalsky, Wolfgang, Johannes, Hans-Hermann
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl(3).nH(2)O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/b807735p