Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-05 (20), p.2334
Hauptverfasser: Hövelmann, Claas H, Streuff, Jan, Brelot, Lydia, Muñiz, Kilian
Format: Artikel
Sprache:eng
Schlagworte:
Amination
Catalysis
Copper - chemistry
Crystallography, X-Ray
Cyclization
Guanidines - chemical synthesis
Guanidines - chemistry
Oxidants - chemistry
Palladium - chemistry
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container_issue 20
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container_title Chemical communications (Cambridge, England)
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creator Hövelmann, Claas H
Streuff, Jan
Brelot, Lydia
Muñiz, Kilian
description Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.
doi_str_mv 10.1039/b719479j
format Article
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Amination
Catalysis
Copper - chemistry
Crystallography, X-Ray
Cyclization
Guanidines - chemical synthesis
Guanidines - chemistry
Oxidants - chemistry
Palladium - chemistry
title Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant
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