Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-05 (20), p.2334
Hauptverfasser: Hövelmann, Claas H, Streuff, Jan, Brelot, Lydia, Muñiz, Kilian
Format: Artikel
Sprache:eng
Schlagworte:
Amination
Catalysis
Copper - chemistry
Crystallography, X-Ray
Cyclization
Guanidines - chemical synthesis
Guanidines - chemistry
Oxidants - chemistry
Palladium - chemistry
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Beschreibung
Zusammenfassung:Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/b719479j