Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2

Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-07 (15), p.1642-1643
Hauptverfasser: Lin, Candy Z-J., Chui, Stephen S-Y., Lo, Samuel M-F., Shek, Fanny L-Y., Wu, Mingmei, Suwinska, Kinga, Lipkowski, Janusz, Williams, Ian D.
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Sprache:eng
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ISSN:1359-7345
1364-548X
DOI:10.1039/b201501n