A polarographic determination of trace amounts of lead in zirconium and its alloys
A method was developed for determining lead in reactor-grade zirconium and zirconium alloys. The procedure involves a preliminary separation of the leaddiethyldithiocarbamate complex and subsequent determination of the metal by using a cathode-ray polarograph. The procedure is satisfactory over the...
Gespeichert in:
Veröffentlicht in: | Analyst 1960-01, Vol.85 (1007), p.139 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 1007 |
container_start_page | 139 |
container_title | Analyst |
container_volume | 85 |
creator | Wood, D. F. Nicholls, H. A. |
description | A method was developed for determining lead in reactor-grade zirconium and zirconium alloys. The procedure involves a preliminary separation of the leaddiethyldithiocarbamate complex and subsequent determination of the metal by using a cathode-ray polarograph. The procedure is satisfactory over the range 20 to 100 ppm of lead. Iron and molybdenum interfere, but interference by amounts up to at least 1 and 2.5%, respectively, can be overcome by a preliminary extraction with diethyl ether from acid solution. (auth) |
doi_str_mv | 10.1039/an9608500139 |
format | Article |
fullrecord | <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1039_an9608500139</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1039_an9608500139</sourcerecordid><originalsourceid>FETCH-LOGICAL-c286t-bbb52edd751ab5371fe0dd1f63e13ddfda0b845d97dc49ccf7b4852c033516a93</originalsourceid><addsrcrecordid>eNpNUEtLxDAYDKLgunrzBwTPVr80Tdocl8UXLAii5_I1DzfSJkuSPay_3sp68DTMg2EYQq4Z3DHg6h6DktAJAMbVCVkwLptKiLo7JQsA4FUtRXNOLnL-mikDAQvytqK7OGKKnwl3W6-pscWmyQcsPgYaHS0JtaU4xX0o-VcYLRrqA_32Scfg9xPFMAuzieMYD_mSnDkcs736wyX5eHx4Xz9Xm9enl_VqU-m6k6UahkHU1phWMBwEb5mzYAxzklvGjXEGYegaYVRrdKO0du3QdKLWwLlgEhVfkptjb8zF91n7YvV2XhSsLn1Tg-SqnkO3x5BOMedkXb9LfsJ06Bn0v6f1_0_jP05IYCk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A polarographic determination of trace amounts of lead in zirconium and its alloys</title><source>Royal Society of Chemistry Journals Archive (1841-2007)</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Wood, D. F. ; Nicholls, H. A.</creator><creatorcontrib>Wood, D. F. ; Nicholls, H. A. ; Imperial Chemical Industries Ltd., Birmingham, Eng</creatorcontrib><description>A method was developed for determining lead in reactor-grade zirconium and zirconium alloys. The procedure involves a preliminary separation of the leaddiethyldithiocarbamate complex and subsequent determination of the metal by using a cathode-ray polarograph. The procedure is satisfactory over the range 20 to 100 ppm of lead. Iron and molybdenum interfere, but interference by amounts up to at least 1 and 2.5%, respectively, can be overcome by a preliminary extraction with diethyl ether from acid solution. (auth)</description><identifier>ISSN: 0003-2654</identifier><identifier>EISSN: 1364-5528</identifier><identifier>DOI: 10.1039/an9608500139</identifier><language>eng</language><subject>ACIDS ; CARBAMATES ; CATHODES ; CHEMISTRY ; COMPLEXES ; DETECTION ; ETHERS ; ETHYL RADICALS ; IMPURITIES ; INSTRUMENTS ; IRON ; LEAD ; LEAD COMPLEXES ; MOLYBDENUM ; ORGANIC SULFUR COMPOUNDS ; POLAROGRAPHY ; QUANTITATIVE ANALYSIS ; SENSITIVITY ; SEPARATION PROCESSES ; SOLUTIONS ; SOLVENT EXTRACTION ; USES ; ZIRCONIUM ; ZIRCONIUM ALLOYS</subject><ispartof>Analyst, 1960-01, Vol.85 (1007), p.139</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-bbb52edd751ab5371fe0dd1f63e13ddfda0b845d97dc49ccf7b4852c033516a93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,881,2818,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/4206392$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Wood, D. F.</creatorcontrib><creatorcontrib>Nicholls, H. A.</creatorcontrib><creatorcontrib>Imperial Chemical Industries Ltd., Birmingham, Eng</creatorcontrib><title>A polarographic determination of trace amounts of lead in zirconium and its alloys</title><title>Analyst</title><description>A method was developed for determining lead in reactor-grade zirconium and zirconium alloys. The procedure involves a preliminary separation of the leaddiethyldithiocarbamate complex and subsequent determination of the metal by using a cathode-ray polarograph. The procedure is satisfactory over the range 20 to 100 ppm of lead. Iron and molybdenum interfere, but interference by amounts up to at least 1 and 2.5%, respectively, can be overcome by a preliminary extraction with diethyl ether from acid solution. (auth)</description><subject>ACIDS</subject><subject>CARBAMATES</subject><subject>CATHODES</subject><subject>CHEMISTRY</subject><subject>COMPLEXES</subject><subject>DETECTION</subject><subject>ETHERS</subject><subject>ETHYL RADICALS</subject><subject>IMPURITIES</subject><subject>INSTRUMENTS</subject><subject>IRON</subject><subject>LEAD</subject><subject>LEAD COMPLEXES</subject><subject>MOLYBDENUM</subject><subject>ORGANIC SULFUR COMPOUNDS</subject><subject>POLAROGRAPHY</subject><subject>QUANTITATIVE ANALYSIS</subject><subject>SENSITIVITY</subject><subject>SEPARATION PROCESSES</subject><subject>SOLUTIONS</subject><subject>SOLVENT EXTRACTION</subject><subject>USES</subject><subject>ZIRCONIUM</subject><subject>ZIRCONIUM ALLOYS</subject><issn>0003-2654</issn><issn>1364-5528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1960</creationdate><recordtype>article</recordtype><recordid>eNpNUEtLxDAYDKLgunrzBwTPVr80Tdocl8UXLAii5_I1DzfSJkuSPay_3sp68DTMg2EYQq4Z3DHg6h6DktAJAMbVCVkwLptKiLo7JQsA4FUtRXNOLnL-mikDAQvytqK7OGKKnwl3W6-pscWmyQcsPgYaHS0JtaU4xX0o-VcYLRrqA_32Scfg9xPFMAuzieMYD_mSnDkcs736wyX5eHx4Xz9Xm9enl_VqU-m6k6UahkHU1phWMBwEb5mzYAxzklvGjXEGYegaYVRrdKO0du3QdKLWwLlgEhVfkptjb8zF91n7YvV2XhSsLn1Tg-SqnkO3x5BOMedkXb9LfsJ06Bn0v6f1_0_jP05IYCk</recordid><startdate>19600101</startdate><enddate>19600101</enddate><creator>Wood, D. F.</creator><creator>Nicholls, H. A.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19600101</creationdate><title>A polarographic determination of trace amounts of lead in zirconium and its alloys</title><author>Wood, D. F. ; Nicholls, H. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-bbb52edd751ab5371fe0dd1f63e13ddfda0b845d97dc49ccf7b4852c033516a93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1960</creationdate><topic>ACIDS</topic><topic>CARBAMATES</topic><topic>CATHODES</topic><topic>CHEMISTRY</topic><topic>COMPLEXES</topic><topic>DETECTION</topic><topic>ETHERS</topic><topic>ETHYL RADICALS</topic><topic>IMPURITIES</topic><topic>INSTRUMENTS</topic><topic>IRON</topic><topic>LEAD</topic><topic>LEAD COMPLEXES</topic><topic>MOLYBDENUM</topic><topic>ORGANIC SULFUR COMPOUNDS</topic><topic>POLAROGRAPHY</topic><topic>QUANTITATIVE ANALYSIS</topic><topic>SENSITIVITY</topic><topic>SEPARATION PROCESSES</topic><topic>SOLUTIONS</topic><topic>SOLVENT EXTRACTION</topic><topic>USES</topic><topic>ZIRCONIUM</topic><topic>ZIRCONIUM ALLOYS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wood, D. F.</creatorcontrib><creatorcontrib>Nicholls, H. A.</creatorcontrib><creatorcontrib>Imperial Chemical Industries Ltd., Birmingham, Eng</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Analyst</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wood, D. F.</au><au>Nicholls, H. A.</au><aucorp>Imperial Chemical Industries Ltd., Birmingham, Eng</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A polarographic determination of trace amounts of lead in zirconium and its alloys</atitle><jtitle>Analyst</jtitle><date>1960-01-01</date><risdate>1960</risdate><volume>85</volume><issue>1007</issue><spage>139</spage><pages>139-</pages><issn>0003-2654</issn><eissn>1364-5528</eissn><abstract>A method was developed for determining lead in reactor-grade zirconium and zirconium alloys. The procedure involves a preliminary separation of the leaddiethyldithiocarbamate complex and subsequent determination of the metal by using a cathode-ray polarograph. The procedure is satisfactory over the range 20 to 100 ppm of lead. Iron and molybdenum interfere, but interference by amounts up to at least 1 and 2.5%, respectively, can be overcome by a preliminary extraction with diethyl ether from acid solution. (auth)</abstract><doi>10.1039/an9608500139</doi></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0003-2654 |
ispartof | Analyst, 1960-01, Vol.85 (1007), p.139 |
issn | 0003-2654 1364-5528 |
language | eng |
recordid | cdi_crossref_primary_10_1039_an9608500139 |
source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | ACIDS CARBAMATES CATHODES CHEMISTRY COMPLEXES DETECTION ETHERS ETHYL RADICALS IMPURITIES INSTRUMENTS IRON LEAD LEAD COMPLEXES MOLYBDENUM ORGANIC SULFUR COMPOUNDS POLAROGRAPHY QUANTITATIVE ANALYSIS SENSITIVITY SEPARATION PROCESSES SOLUTIONS SOLVENT EXTRACTION USES ZIRCONIUM ZIRCONIUM ALLOYS |
title | A polarographic determination of trace amounts of lead in zirconium and its alloys |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T07%3A16%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20polarographic%20determination%20of%20trace%20amounts%20of%20lead%20in%20zirconium%20and%20its%20alloys&rft.jtitle=Analyst&rft.au=Wood,%20D.%20F.&rft.aucorp=Imperial%20Chemical%20Industries%20Ltd.,%20Birmingham,%20Eng&rft.date=1960-01-01&rft.volume=85&rft.issue=1007&rft.spage=139&rft.pages=139-&rft.issn=0003-2654&rft.eissn=1364-5528&rft_id=info:doi/10.1039/an9608500139&rft_dat=%3Ccrossref_osti_%3E10_1039_an9608500139%3C/crossref_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |