Correlation of the redox properties and stereochemical features of copper complexes of [18]aneN 2 S 4 (1,4,10,13-tetrathia-7,16-diazacyclooctadecane) and its N,N′-dimethyl derivative Me 2 [18]aneN 2 S 4 . Crystal structures of [Cu II ([18]aneN 2 S 4 )][ClO 4 ] 2 ·H 2 O, [Cu II (Me 2 [18]aneN 2 S 4 )][PF 6 ] 2 , [Cu I2 ([18]aneN 2 S 4 )]BPh 4 , [Cu I (Me 2 [18]aneN 2 S 4 )]PF 6 and [Cu I 2 (Me 2 [18]aneN 2 S 4 )(NCMe) 2 ][PF 6 ] 2

Correlation of the redox properties and stereochemical features of copper complexes of [18]aneN 2 S 4 (1,4,10,13-tetrathia-7,16-diazacyclooctadecane) and its N,N′-dimethyl derivative Me 2 [18]aneN 2 S 4 . Crystal structures of [Cu II ([18]aneN 2 S 4 )][ClO 4 ] 2 ·H 2 O, [Cu II (Me 2 [18]aneN 2 S 4 )][PF 6 ] 2 , [Cu I2 ([18]aneN 2 S 4 )]BPh 4 , [Cu I (Me 2 [18]aneN 2 S 4 )]PF 6 and [Cu I 2 (Me 2 [18]aneN 2 S 4 )(NCMe) 2 ][PF 6 ] 2

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Veröffentlicht in:Journal of the Chemical Society. Dalton transactions 1992 (20), p.2993-3002
Hauptverfasser: Atkinson, Nigel, Blake, Alexander J., Drew, Michael G. B., Forsyth, George, Gould, Robert O., Lavery, Aidan J., Reid, Gillian, Schröder, Martin
Format: Artikel
Sprache:eng
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ISSN:0300-9246
1364-5447
DOI:10.1039/DT9920002993