Transformation of a methyleneamide ligand at molybdenum : electrochemical oxidation to a cyanide, reactions with elemental oxygen, sulphur or selenium and X-ray crystal structures of trans-[Mo(CN)Cl(dppe)2]•MeOH and trans-[Mo(NCS)Cl(dppe)2]; electroreduction of the cyanide to an aminocarbyne, trans-[Mo(CNH2)Cl(dppe)2] (dppe=Ph2PCH2CH2PPh2)

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the Chemical Society. Dalton transactions 1991 (1), p.121-129
Hauptverfasser:	HILLS, A, HUGHES, D. L, MACDONALD, C. J, MOHAMMED, M. Y, PICKETT, C. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives
Online-Zugang:	Volltext
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