Carbene complexes. Part 16. Synthesis and properties of NN′N″N‴-tetra-aryl-substituted electron-rich olefin-derived carbeneruthenium( II ) complexes containing a spontaneously formed ortho-metallated-N-arylcarbene ligand; the crystal and molecular structures of [RuCl{CN(C 6 H 4 Me-4)CH 2 CH 2 NC 6 H 3 Me-4}(PEt 3 ) 2 ](6) and [Ru(CO)Cl{CN(C 6 H 4 Me-4)CH 2 CH 2 NC 6 H 3 Me-4}(PEt 3 ) 2 ](16)

Carbene complexes. Part 16. Synthesis and properties of NN′N″N‴-tetra-aryl-substituted electron-rich olefin-derived carbeneruthenium( II ) complexes containing a spontaneously formed ortho-metallated-N-arylcarbene ligand; the crystal and molecular structures of [RuCl{CN(C 6 H 4 Me-4)CH 2 CH 2 NC 6 H 3 Me-4}(PEt 3 ) 2 ](6) and [Ru(CO)Cl{CN(C 6 H 4 Me-4)CH 2 CH 2 NC 6 H 3 Me-4}(PEt 3 ) 2 ](16)

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Veröffentlicht in:Journal of the Chemical Society. Dalton transactions 1979 (12), p.1929-1942
Hauptverfasser: Hitchcock, Peter B., Lappert, Michael F., Pye, Peter L., Thomas, Sunday
Format: Artikel
Sprache:eng
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ISSN:0300-9246
1364-5447
DOI:10.1039/DT9790001929