Nonylphenol polybenzoxazines-derived nitrogen-rich porous carbon (NRPC)-supported g-C 3 N 4 /Fe 3 O 4 nanocomposite for efficient high-performance supercapacitor application
In this work, a straightforward and scalable method was used to generate nitrogen-rich porous carbon (NRPC), which was then incorporated with a graphitic carbon nitride and magnetite (g-C N /Fe O ) nanocomposite, fabricated with Fe O nanoparticles as an eco-friendly and economically viable component...
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Veröffentlicht in: | Soft matter 2024-10, Vol.20 (39), p.7957-7969 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this work, a straightforward and scalable method was used to generate nitrogen-rich porous carbon (NRPC), which was then incorporated with a graphitic carbon nitride and magnetite (g-C
N
/Fe
O
) nanocomposite, fabricated with Fe
O
nanoparticles as an eco-friendly and economically viable component. The fabricated NRPC/g-C
N
/Fe
O
nanocomposite was applied as an electrode in supercapacitor applications. The synthesized NRPC/g-C
N
/Fe
O
nanocomposite, NRPC, g-C
N
, and Fe
O
were characterized by analytical and morphological analyses. The spherically shaped Fe
O
nanoparticles were analyzed by field-emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HR-TEM). The specific surface area of NRPC/g-C
N
/Fe
O
was determined to be 479 m
g
. All the crosslinked composites showed exceptional electrochemical performance and exhibited a pseudo-capacitance behaviour. In comparison to the Fe
O
and g-C
N
/Fe
O
electrodes, the NRPC/g-C
N
/Fe
O
electrode showed a lower charge-transfer resistance and higher capacitance. The prepared NRPC/g-C
N
/Fe
O
electrode exhibited the highest specific capacitance of 385 F g
at 1 A g
compared to Fe
O
(112 F g
) and g-C
N
/Fe
O
(150 F g
). Furthermore, the cycling efficiency of NRPC/g-C
N
/Fe
O
remained at 94.3% even after 2000 cycles. The introduction of NRPC to g-C
N
/Fe
O
improved its suitability for application in high-performance supercapacitors. |
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ISSN: | 1744-683X 1744-6848 |
DOI: | 10.1039/D4SM00920G |