Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesop...

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Veröffentlicht in:RSC advances 2024-02, Vol.14 (11), p.7728-7739
Hauptverfasser: Mangesh, V. L, Perumal, Tamizhdurai, Santhosh, S, Siva Kumar, Nadavala, Vijayaraj, A, Kumar, G. S. V. Seshu, Sugumaran, S, Murali, G, Basivi, Praveen Kumar, Al-Fatesh, Ahmed S
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Sprache:eng
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Zusammenfassung:This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesoporous ZSM-5 were created via reverse order impregnation to facilitate HDO of non-edible oils. Techniques such as XRD, FT-IR, BET, HR-TEM, HR-SEM, TPD, and TGA were used to characterize the produced catalysts. The synthesized catalysts considerably influenced the hydrodeoxygenation activities for the synthesis of lengthy chain hydrocarbons in a stainless-steel reactor with a high-pressure fixed bed between 300 and 375 °C under 10-40 bar hydrogen pressure. High levels of Ni/Pt-ZSM-5 acidity, textural, and H 2 consumption qualities were discovered. Distributions of the products were also reviewed, along with comparisons of the structure-activity connections. This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst.
ISSN:2046-2069
2046-2069
DOI:10.1039/d4ra00346b