Mononuclear Fe() Schiff base antipyrine complexes for catalytic hydrogen generation

Mononuclear Fe( iii ) complexes containing an antipyrine Schiff base ligand were prepared and fully characterized, demonstrating a planar tetradentate coordination geometry. These complexes were found to be active for the hydrogen evolution reaction. Catalysis occurs at −1.4 V vs. Fc + /Fc, with an overpotential of 700 mV. The complexes are active electrocatalysts with a turnover frequency of 700 s −1 . Furthermore, when paired with a chromophore and sacrificial donor, the complexes are active photocatalysts demonstrating >1700 turnovers during 40 hours of irradiation with a quantum yield of up to 5.4%. The catalysts have also been found to operate in natural water samples of varying salinity. Mononuclear Fe( iii ) complexes containing an antipyrine Schiff base ligand were prepared and fully characterized, demonstrating a planar tetradentate coordination geometry. The resulting complexes are active for HER with possible ligand cooperativity.