Reaction of Ph 2 C(X)(CO 2 H) (X = OH, NH 2 ) with [VO(OR) 3 ] (R = Et, n Pr): structure, magnetic susceptibility and ROP capability

Reaction of Ph 2 C(X)(CO 2 H) (X = OH, NH 2 ) with [VO(OR) 3 ] (R = Et, n Pr): structure, magnetic susceptibility and ROP capability

Reaction of [VO(OR) ] (R = Et, Pr) with 2,2'-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(μ-OR)][Ph C(NH )(CO )]} , whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V (O) M(OR) [Ph C(OH)(CO )] } (M =

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024-03, Vol.53 (12), p.5351-5355
Hauptverfasser: Glenister, Mollie A, Frese, Josef W A, Elsegood, Mark R J, Canaj, Angelos B, Brechin, Euan K, Redshaw, Carl
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of [VO(OR) ] (R = Et, Pr) with 2,2'-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(μ-OR)][Ph C(NH )(CO )]} , whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V (O) M(OR) [Ph C(OH)(CO )] } (M =
ISSN:1477-9226
1477-9234
DOI:10.1039/d4dt00078a