Fluorinated vs. non-fluorinated tetrahedral Tri 4 Tri 4 porous organic cages for H 2 , CO 2 , and CH 4 adsorption

Fluorinated vs. non-fluorinated tetrahedral Tri 4 Tri 4 porous organic cages for H 2 , CO 2 , and CH 4 adsorption

We present the synthesis of two porous complementary tetrahedral Tri Tri imine cages, exhibiting Brunauer-Emmett-Teller (BET) surface areas of 591 m g and 753 m g , suitable for the adsorption of H , CO , and CH . Comparisons in terms of crystallinity, thermal stability, porosity, and selectivity hi...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-12, Vol.60 (99), p.14762-14765
Hauptverfasser: David, Tim, Oestreich, Robert, Pausch, Tobias, Wada, Yuki, Fleck-Kunde, Tom, Kawano, Masaki, Janiak, Christoph, Schmidt, Bernd M
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Sprache:eng
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Zusammenfassung:We present the synthesis of two porous complementary tetrahedral Tri Tri imine cages, exhibiting Brunauer-Emmett-Teller (BET) surface areas of 591 m g and 753 m g , suitable for the adsorption of H , CO , and CH . Comparisons in terms of crystallinity, thermal stability, porosity, and selectivity highlight the promising properties of fluorinated and non-fluorinated porous organic cages as functional materials.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc05277c