Aminoarylation of alkynes using diarylanilines

Aminoarylation of alkynes using diarylanilines

Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products ar...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-06, Vol.6 (49), p.6296-6299
Hauptverfasser: Liu, Zi, Greaney, Michael F
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Aniline
Reagents
Transition metals
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Zusammenfassung:Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles. Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc01935k