Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors
Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcry...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2024-08, Vol.12 (32), p.21134-21147 |
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| creator | Suman, Shradha Sharma, Dhananjay Kumar Szabo, Ondrej Rakesh, Benadict Marton, Marian Vojs, Marian Vincze, Andrej Dutta, Soumya Prakash Balaji, Umapathi Debasish, Debidutta Sakthivel, Ramasamy Sankaran, Kamatchi Jothiramalingam Kromka, Alexander |
| description | Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcrystalline diamond (BMCD) and boron-doped ultra-nanocrystalline diamond (BUNCD), are employed for nanostructuring. The diamond nanopillars are fabricated
via
the Au mask-assisted reactive ion etching (RIE) method. The nanostructured samples of BMCD and BUNCD are termed BMCD
N
and BUNCD
N
. The Raman spectroscopy and X-ray photoelectron spectroscopy measurements of these nanostructured samples confirm the presence of sp
2
in sp
3
-bonded carbon, which combine to offer good EC activity of sp
2
and exceptional stability of sp
3
carbon. These nanostructured BDD samples with enhanced surface area are utilized as electrode materials to construct an electric double-layer capacitor and pseudocapacitor. In 1 M Na
2
SO
4
solution, the maximum specific capacitance of BMCD
N
is found to be 0.0852 mF cm
−2
, whereas, for BUNCD
N
the value is 0.0784 mF cm
−2
. The electrochemical analysis of these samples shows they exhibit superior electron transfer kinetics with 80% capacitance retention after 2000 cycles, which indicates the suitable utilization of these nanostructured samples as electrodes in EC supercapacitors.
Nanostructuring boron-doped diamond effectively improves the electrochemical supercapacitor performance with high lifetime stability. |
| doi_str_mv | 10.1039/d3ta07728d |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_D3TA07728D</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3092369165</sourcerecordid><originalsourceid>FETCH-LOGICAL-c170t-bf9fbbb8fef7540bfc9cce7962392d1fe9d243eef1c941dc5a6cb0732ed59e063</originalsourceid><addsrcrecordid>eNpFkM1LAzEQxYMoWGov3oUFb8JqstmvHEvrFxS8VK9LdjJpU7abNcmC_e_dulrnMm-Y37yBR8g1o_eMcvGgeJC0KJJSnZFJQjMaF6nIz0-6LC_JzPsdHaqkNBdiQr4-0AUDsmkOkWzMpkUV1dbZNla2G7Qycm9bFbWytT64HkLv0EfSR1uz2Q5HqLUBg22IsEEIzqphra37G2GL-6N_5PsOHchOggnW-StyoWXjcfbbp-T96XG9eIlXb8-vi_kqBlbQENda6LquS426yFJaaxAAWIg84SJRTKNQScoRNQORMgWZzKGmBU9QZQJpzqfkdvTtnP3s0YdqZ3vXDi8rTkXCc8HybKDuRgqc9d6hrjpn9tIdKkarY7jVkq_nP-EuB_hmhJ2HE_cfPv8GC896nw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3092369165</pqid></control><display><type>article</type><title>Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors</title><source>Royal Society Of Chemistry Journals</source><creator>Suman, Shradha ; Sharma, Dhananjay Kumar ; Szabo, Ondrej ; Rakesh, Benadict ; Marton, Marian ; Vojs, Marian ; Vincze, Andrej ; Dutta, Soumya Prakash ; Balaji, Umapathi ; Debasish, Debidutta ; Sakthivel, Ramasamy ; Sankaran, Kamatchi Jothiramalingam ; Kromka, Alexander</creator><creatorcontrib>Suman, Shradha ; Sharma, Dhananjay Kumar ; Szabo, Ondrej ; Rakesh, Benadict ; Marton, Marian ; Vojs, Marian ; Vincze, Andrej ; Dutta, Soumya Prakash ; Balaji, Umapathi ; Debasish, Debidutta ; Sakthivel, Ramasamy ; Sankaran, Kamatchi Jothiramalingam ; Kromka, Alexander</creatorcontrib><description>Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcrystalline diamond (BMCD) and boron-doped ultra-nanocrystalline diamond (BUNCD), are employed for nanostructuring. The diamond nanopillars are fabricated
via
the Au mask-assisted reactive ion etching (RIE) method. The nanostructured samples of BMCD and BUNCD are termed BMCD
N
and BUNCD
N
. The Raman spectroscopy and X-ray photoelectron spectroscopy measurements of these nanostructured samples confirm the presence of sp
2
in sp
3
-bonded carbon, which combine to offer good EC activity of sp
2
and exceptional stability of sp
3
carbon. These nanostructured BDD samples with enhanced surface area are utilized as electrode materials to construct an electric double-layer capacitor and pseudocapacitor. In 1 M Na
2
SO
4
solution, the maximum specific capacitance of BMCD
N
is found to be 0.0852 mF cm
−2
, whereas, for BUNCD
N
the value is 0.0784 mF cm
−2
. The electrochemical analysis of these samples shows they exhibit superior electron transfer kinetics with 80% capacitance retention after 2000 cycles, which indicates the suitable utilization of these nanostructured samples as electrodes in EC supercapacitors.
Nanostructuring boron-doped diamond effectively improves the electrochemical supercapacitor performance with high lifetime stability.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/d3ta07728d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Boron ; Capacitance ; Carbon ; Diamonds ; Electrical conductivity ; Electrical resistivity ; Electrochemical analysis ; Electrochemistry ; Electrode materials ; Electrodes ; Electron transfer ; Electrons ; Etching ; Nanostructure ; Photoelectron spectroscopy ; Photoelectrons ; Raman spectroscopy ; Reactive ion etching ; Sodium sulfate ; Spectroscopy ; Spectrum analysis ; Supercapacitors ; Surface stability ; X ray photoelectron spectroscopy</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2024-08, Vol.12 (32), p.21134-21147</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-bf9fbbb8fef7540bfc9cce7962392d1fe9d243eef1c941dc5a6cb0732ed59e063</cites><orcidid>0000-0003-0241-4648 ; 0000-0002-0758-3603 ; 0000-0001-6329-9749 ; 0000-0002-3531-6748 ; 0000-0001-7784-9780 ; 0000-0002-4468-0541</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Suman, Shradha</creatorcontrib><creatorcontrib>Sharma, Dhananjay Kumar</creatorcontrib><creatorcontrib>Szabo, Ondrej</creatorcontrib><creatorcontrib>Rakesh, Benadict</creatorcontrib><creatorcontrib>Marton, Marian</creatorcontrib><creatorcontrib>Vojs, Marian</creatorcontrib><creatorcontrib>Vincze, Andrej</creatorcontrib><creatorcontrib>Dutta, Soumya Prakash</creatorcontrib><creatorcontrib>Balaji, Umapathi</creatorcontrib><creatorcontrib>Debasish, Debidutta</creatorcontrib><creatorcontrib>Sakthivel, Ramasamy</creatorcontrib><creatorcontrib>Sankaran, Kamatchi Jothiramalingam</creatorcontrib><creatorcontrib>Kromka, Alexander</creatorcontrib><title>Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcrystalline diamond (BMCD) and boron-doped ultra-nanocrystalline diamond (BUNCD), are employed for nanostructuring. The diamond nanopillars are fabricated
via
the Au mask-assisted reactive ion etching (RIE) method. The nanostructured samples of BMCD and BUNCD are termed BMCD
N
and BUNCD
N
. The Raman spectroscopy and X-ray photoelectron spectroscopy measurements of these nanostructured samples confirm the presence of sp
2
in sp
3
-bonded carbon, which combine to offer good EC activity of sp
2
and exceptional stability of sp
3
carbon. These nanostructured BDD samples with enhanced surface area are utilized as electrode materials to construct an electric double-layer capacitor and pseudocapacitor. In 1 M Na
2
SO
4
solution, the maximum specific capacitance of BMCD
N
is found to be 0.0852 mF cm
−2
, whereas, for BUNCD
N
the value is 0.0784 mF cm
−2
. The electrochemical analysis of these samples shows they exhibit superior electron transfer kinetics with 80% capacitance retention after 2000 cycles, which indicates the suitable utilization of these nanostructured samples as electrodes in EC supercapacitors.
Nanostructuring boron-doped diamond effectively improves the electrochemical supercapacitor performance with high lifetime stability.</description><subject>Boron</subject><subject>Capacitance</subject><subject>Carbon</subject><subject>Diamonds</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electron transfer</subject><subject>Electrons</subject><subject>Etching</subject><subject>Nanostructure</subject><subject>Photoelectron spectroscopy</subject><subject>Photoelectrons</subject><subject>Raman spectroscopy</subject><subject>Reactive ion etching</subject><subject>Sodium sulfate</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Supercapacitors</subject><subject>Surface stability</subject><subject>X ray photoelectron spectroscopy</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkM1LAzEQxYMoWGov3oUFb8JqstmvHEvrFxS8VK9LdjJpU7abNcmC_e_dulrnMm-Y37yBR8g1o_eMcvGgeJC0KJJSnZFJQjMaF6nIz0-6LC_JzPsdHaqkNBdiQr4-0AUDsmkOkWzMpkUV1dbZNla2G7Qycm9bFbWytT64HkLv0EfSR1uz2Q5HqLUBg22IsEEIzqphra37G2GL-6N_5PsOHchOggnW-StyoWXjcfbbp-T96XG9eIlXb8-vi_kqBlbQENda6LquS426yFJaaxAAWIg84SJRTKNQScoRNQORMgWZzKGmBU9QZQJpzqfkdvTtnP3s0YdqZ3vXDi8rTkXCc8HybKDuRgqc9d6hrjpn9tIdKkarY7jVkq_nP-EuB_hmhJ2HE_cfPv8GC896nw</recordid><startdate>20240813</startdate><enddate>20240813</enddate><creator>Suman, Shradha</creator><creator>Sharma, Dhananjay Kumar</creator><creator>Szabo, Ondrej</creator><creator>Rakesh, Benadict</creator><creator>Marton, Marian</creator><creator>Vojs, Marian</creator><creator>Vincze, Andrej</creator><creator>Dutta, Soumya Prakash</creator><creator>Balaji, Umapathi</creator><creator>Debasish, Debidutta</creator><creator>Sakthivel, Ramasamy</creator><creator>Sankaran, Kamatchi Jothiramalingam</creator><creator>Kromka, Alexander</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-0241-4648</orcidid><orcidid>https://orcid.org/0000-0002-0758-3603</orcidid><orcidid>https://orcid.org/0000-0001-6329-9749</orcidid><orcidid>https://orcid.org/0000-0002-3531-6748</orcidid><orcidid>https://orcid.org/0000-0001-7784-9780</orcidid><orcidid>https://orcid.org/0000-0002-4468-0541</orcidid></search><sort><creationdate>20240813</creationdate><title>Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors</title><author>Suman, Shradha ; Sharma, Dhananjay Kumar ; Szabo, Ondrej ; Rakesh, Benadict ; Marton, Marian ; Vojs, Marian ; Vincze, Andrej ; Dutta, Soumya Prakash ; Balaji, Umapathi ; Debasish, Debidutta ; Sakthivel, Ramasamy ; Sankaran, Kamatchi Jothiramalingam ; Kromka, Alexander</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-bf9fbbb8fef7540bfc9cce7962392d1fe9d243eef1c941dc5a6cb0732ed59e063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Boron</topic><topic>Capacitance</topic><topic>Carbon</topic><topic>Diamonds</topic><topic>Electrical conductivity</topic><topic>Electrical resistivity</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electron transfer</topic><topic>Electrons</topic><topic>Etching</topic><topic>Nanostructure</topic><topic>Photoelectron spectroscopy</topic><topic>Photoelectrons</topic><topic>Raman spectroscopy</topic><topic>Reactive ion etching</topic><topic>Sodium sulfate</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Supercapacitors</topic><topic>Surface stability</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Suman, Shradha</creatorcontrib><creatorcontrib>Sharma, Dhananjay Kumar</creatorcontrib><creatorcontrib>Szabo, Ondrej</creatorcontrib><creatorcontrib>Rakesh, Benadict</creatorcontrib><creatorcontrib>Marton, Marian</creatorcontrib><creatorcontrib>Vojs, Marian</creatorcontrib><creatorcontrib>Vincze, Andrej</creatorcontrib><creatorcontrib>Dutta, Soumya Prakash</creatorcontrib><creatorcontrib>Balaji, Umapathi</creatorcontrib><creatorcontrib>Debasish, Debidutta</creatorcontrib><creatorcontrib>Sakthivel, Ramasamy</creatorcontrib><creatorcontrib>Sankaran, Kamatchi Jothiramalingam</creatorcontrib><creatorcontrib>Kromka, Alexander</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Suman, Shradha</au><au>Sharma, Dhananjay Kumar</au><au>Szabo, Ondrej</au><au>Rakesh, Benadict</au><au>Marton, Marian</au><au>Vojs, Marian</au><au>Vincze, Andrej</au><au>Dutta, Soumya Prakash</au><au>Balaji, Umapathi</au><au>Debasish, Debidutta</au><au>Sakthivel, Ramasamy</au><au>Sankaran, Kamatchi Jothiramalingam</au><au>Kromka, Alexander</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2024-08-13</date><risdate>2024</risdate><volume>12</volume><issue>32</issue><spage>21134</spage><epage>21147</epage><pages>21134-21147</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcrystalline diamond (BMCD) and boron-doped ultra-nanocrystalline diamond (BUNCD), are employed for nanostructuring. The diamond nanopillars are fabricated
via
the Au mask-assisted reactive ion etching (RIE) method. The nanostructured samples of BMCD and BUNCD are termed BMCD
N
and BUNCD
N
. The Raman spectroscopy and X-ray photoelectron spectroscopy measurements of these nanostructured samples confirm the presence of sp
2
in sp
3
-bonded carbon, which combine to offer good EC activity of sp
2
and exceptional stability of sp
3
carbon. These nanostructured BDD samples with enhanced surface area are utilized as electrode materials to construct an electric double-layer capacitor and pseudocapacitor. In 1 M Na
2
SO
4
solution, the maximum specific capacitance of BMCD
N
is found to be 0.0852 mF cm
−2
, whereas, for BUNCD
N
the value is 0.0784 mF cm
−2
. The electrochemical analysis of these samples shows they exhibit superior electron transfer kinetics with 80% capacitance retention after 2000 cycles, which indicates the suitable utilization of these nanostructured samples as electrodes in EC supercapacitors.
Nanostructuring boron-doped diamond effectively improves the electrochemical supercapacitor performance with high lifetime stability.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3ta07728d</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0003-0241-4648</orcidid><orcidid>https://orcid.org/0000-0002-0758-3603</orcidid><orcidid>https://orcid.org/0000-0001-6329-9749</orcidid><orcidid>https://orcid.org/0000-0002-3531-6748</orcidid><orcidid>https://orcid.org/0000-0001-7784-9780</orcidid><orcidid>https://orcid.org/0000-0002-4468-0541</orcidid></addata></record> |
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| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2024-08, Vol.12 (32), p.21134-21147 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_D3TA07728D |
| source | Royal Society Of Chemistry Journals |
| subjects | Boron Capacitance Carbon Diamonds Electrical conductivity Electrical resistivity Electrochemical analysis Electrochemistry Electrode materials Electrodes Electron transfer Electrons Etching Nanostructure Photoelectron spectroscopy Photoelectrons Raman spectroscopy Reactive ion etching Sodium sulfate Spectroscopy Spectrum analysis Supercapacitors Surface stability X ray photoelectron spectroscopy |
| title | Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors |
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