Vertically aligned boron-doped diamond nanostructures as highly efficient electrodes for electrochemical supercapacitors

Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcry...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2024-08, Vol.12 (32), p.21134-21147
Hauptverfasser: Suman, Shradha, Sharma, Dhananjay Kumar, Szabo, Ondrej, Rakesh, Benadict, Marton, Marian, Vojs, Marian, Vincze, Andrej, Dutta, Soumya Prakash, Balaji, Umapathi, Debasish, Debidutta, Sakthivel, Ramasamy, Sankaran, Kamatchi Jothiramalingam, Kromka, Alexander
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Nanostructured boron-doped diamond (BDD) offers a sizeable ion-accessible area, high mechanical robustness, and high electrical conductivity, and could be a suitable electrode for high-performance electrochemical (EC) supercapacitors. Herein, two morphological BDD films, namely, boron-doped microcrystalline diamond (BMCD) and boron-doped ultra-nanocrystalline diamond (BUNCD), are employed for nanostructuring. The diamond nanopillars are fabricated via the Au mask-assisted reactive ion etching (RIE) method. The nanostructured samples of BMCD and BUNCD are termed BMCD N and BUNCD N . The Raman spectroscopy and X-ray photoelectron spectroscopy measurements of these nanostructured samples confirm the presence of sp 2 in sp 3 -bonded carbon, which combine to offer good EC activity of sp 2 and exceptional stability of sp 3 carbon. These nanostructured BDD samples with enhanced surface area are utilized as electrode materials to construct an electric double-layer capacitor and pseudocapacitor. In 1 M Na 2 SO 4 solution, the maximum specific capacitance of BMCD N is found to be 0.0852 mF cm −2 , whereas, for BUNCD N the value is 0.0784 mF cm −2 . The electrochemical analysis of these samples shows they exhibit superior electron transfer kinetics with 80% capacitance retention after 2000 cycles, which indicates the suitable utilization of these nanostructured samples as electrodes in EC supercapacitors. Nanostructuring boron-doped diamond effectively improves the electrochemical supercapacitor performance with high lifetime stability.
ISSN:2050-7488
2050-7496
DOI:10.1039/d3ta07728d