Composite MAX phase/MXene/Ni electrodes with a porous 3D structure for hydrogen evolution and energy storage application

MXenes, a family of two-dimensional (2D) transition metal carbides, have been discovered as exciting candidates for various energy storage and conversion applications, including green hydrogen production by water splitting. Today, these materials mostly remain interesting objects for in-depth fundam...

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Veröffentlicht in:RSC advances 2024-01, Vol.14 (5), p.352-369
Hauptverfasser: Sergiienko, Sergii A, Lajaunie, Luc, Rodríguez-Castellón, Enrique, Constantinescu, Gabriel, Lopes, Daniela V, Shcherban, Nataliya D, Calvino, José J, Labrincha, João A, Sofer, Zdenek, Kovalevsky, Andrei V
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container_end_page 369
container_issue 5
container_start_page 352
container_title RSC advances
container_volume 14
creator Sergiienko, Sergii A
Lajaunie, Luc
Rodríguez-Castellón, Enrique
Constantinescu, Gabriel
Lopes, Daniela V
Shcherban, Nataliya D
Calvino, José J
Labrincha, João A
Sofer, Zdenek
Kovalevsky, Andrei V
description MXenes, a family of two-dimensional (2D) transition metal carbides, have been discovered as exciting candidates for various energy storage and conversion applications, including green hydrogen production by water splitting. Today, these materials mostly remain interesting objects for in-depth fundamental studies and scientific curiosity due to issues related to their preparation and environmental stability, limiting potential industrial applications. This work proposes a simple and inexpensive concept of composite electrodes composed of molybdenum- and titanium-containing MAX phases and MXene as functional materials. The concept is based on the modification of the initial MAX phase by the addition of metallic Ni, tuning Al- and carbon content and synthesis conditions, followed by fluoride-free etching under alkaline conditions. The proposed methodology allows producing a composite electrode with a well-developed 3D porous MAX phase-based structure acting as a support for electrocatalytic species, including MXene, and possessing good mechanical integrity. Electrochemical tests have shown a high electrochemical activity of such electrodes towards the hydrogen evolution reaction (HER), combined with a relatively high areal capacitance (up to 10 F cm −2 ). The MAX phase/MXene/Ni composite with 3D porous structure prepared was assessed for energy conversion and storage application, using the hydrogen evolution reaction under alkaline conditions as a model system.
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Electrochemical tests have shown a high electrochemical activity of such electrodes towards the hydrogen evolution reaction (HER), combined with a relatively high areal capacitance (up to 10 F cm −2 ). 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Electrochemical tests have shown a high electrochemical activity of such electrodes towards the hydrogen evolution reaction (HER), combined with a relatively high areal capacitance (up to 10 F cm −2 ). 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subjects Carbon content
Chemistry
Electrodes
Energy storage
Functional materials
Green hydrogen
Hydrogen evolution reactions
Hydrogen production
Industrial applications
Metal carbides
MXenes
Nickel
Titanium
Transition metals
Water splitting
title Composite MAX phase/MXene/Ni electrodes with a porous 3D structure for hydrogen evolution and energy storage application
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