Composite MAX phase/MXene/Ni electrodes with a porous 3D structure for hydrogen evolution and energy storage application

MXenes, a family of two-dimensional (2D) transition metal carbides, have been discovered as exciting candidates for various energy storage and conversion applications, including green hydrogen production by water splitting. Today, these materials mostly remain interesting objects for in-depth fundam...

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Veröffentlicht in:RSC advances 2024-01, Vol.14 (5), p.352-369
Hauptverfasser: Sergiienko, Sergii A, Lajaunie, Luc, Rodríguez-Castellón, Enrique, Constantinescu, Gabriel, Lopes, Daniela V, Shcherban, Nataliya D, Calvino, José J, Labrincha, João A, Sofer, Zdenek, Kovalevsky, Andrei V
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Sprache:eng
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Zusammenfassung:MXenes, a family of two-dimensional (2D) transition metal carbides, have been discovered as exciting candidates for various energy storage and conversion applications, including green hydrogen production by water splitting. Today, these materials mostly remain interesting objects for in-depth fundamental studies and scientific curiosity due to issues related to their preparation and environmental stability, limiting potential industrial applications. This work proposes a simple and inexpensive concept of composite electrodes composed of molybdenum- and titanium-containing MAX phases and MXene as functional materials. The concept is based on the modification of the initial MAX phase by the addition of metallic Ni, tuning Al- and carbon content and synthesis conditions, followed by fluoride-free etching under alkaline conditions. The proposed methodology allows producing a composite electrode with a well-developed 3D porous MAX phase-based structure acting as a support for electrocatalytic species, including MXene, and possessing good mechanical integrity. Electrochemical tests have shown a high electrochemical activity of such electrodes towards the hydrogen evolution reaction (HER), combined with a relatively high areal capacitance (up to 10 F cm −2 ). The MAX phase/MXene/Ni composite with 3D porous structure prepared was assessed for energy conversion and storage application, using the hydrogen evolution reaction under alkaline conditions as a model system.
ISSN:2046-2069
2046-2069
DOI:10.1039/d3ra07335a