Magnetocaloric effect and critical behavior of the La 0.75 Ca 0.1 Na 0.15 MnO 3 compound
In this paper, we have studied the critical behavior and the magnetocaloric effect (MCE) simulation for the La Ca Na MnO (LCNMO) compound at the second order ferromagnetic-paramagnetic phase transition. The optimized critical exponents, based on the Kouvel-Fisher method, were found to be: = 0.48 and...
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Veröffentlicht in: | RSC advances 2023-05, Vol.13 (24), p.16529-16535 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this paper, we have studied the critical behavior and the magnetocaloric effect (MCE) simulation for the La
Ca
Na
MnO
(LCNMO) compound at the second order ferromagnetic-paramagnetic phase transition. The optimized critical exponents, based on the Kouvel-Fisher method, were found to be:
= 0.48 and
= 1. These obtained values supposed that the Mean Field Model (MFM) is the proper model to analyze adequately the MCE in the LCNMO sample. The isothermal magnetization
(
,
) and the magnetic entropy change -Δ
(
,
) curves were successfully simulated using three models, namely the Arrott-Noakes equation (ANE) of state, Landau theory, and MFM. The framework of the MFM allows us to estimate magnetic entropy variation in a wide temperature range within the thermodynamics of the model and without using the usual numerical integration of Maxwell relation. |
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ISSN: | 2046-2069 2046-2069 |
DOI: | 10.1039/D3RA02443A |