Proton transfer network with luminescence display controls OFF/ON catalysis that generates a high-speed slider-on-deck

Proton transfer network with luminescence display controls OFF/ON catalysis that generates a high-speed slider-on-deck

A three-component network for OFF/ON catalysis was built from a protonated nanoswitch and a luminophore. Its activation by addition of silver( i ) triggered the proton-catalyzed formation of a biped and the assembly of a fast slider-on-deck ( k 298 = 540 kHz). Upon addition/removal of silver( i ) io...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2023-02, Vol.13 (8), p.5168-5171
Hauptverfasser: Kundu, Sohom, Valiyev, Isa, Mondal, Debabrata, Rajasekaran, Vishnu Verman, Goswami, Abir, Schmittel, Michael
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemistry
Decks
Protons
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A three-component network for OFF/ON catalysis was built from a protonated nanoswitch and a luminophore. Its activation by addition of silver( i ) triggered the proton-catalyzed formation of a biped and the assembly of a fast slider-on-deck ( k 298 = 540 kHz). Upon addition/removal of silver( i ) ions and due to efficient inter-component communication, a supramolecular multicomponent network acts as an OFF/ON proton relay with luminescence display enabling switchable catalysis.
ISSN:2046-2069
2046-2069
DOI:10.1039/d3ra00062a