Benz[ e ]indenyl and benz[ f ]indenyl molybdenum compounds: evidence of the η 3 -coordination mode
This study reports the synthesis and characterization of new molybdenum compounds bearing benz[ e ]indenyl and benz[ f ]indenyl ligands. The capability of the ligands to undergo η 5 -to-η 3 haptotropic rearrangement was evidenced on reactions with tris(pyrazolyl)methane. Appearance of the η 3 -coord...
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| Veröffentlicht in: | New journal of chemistry 2023-11, Vol.47 (46), p.21396-21403 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | This study reports the synthesis and characterization of new molybdenum compounds bearing benz[
e
]indenyl and benz[
f
]indenyl ligands. The capability of the ligands to undergo η
5
-to-η
3
haptotropic rearrangement was evidenced on reactions with tris(pyrazolyl)methane. Appearance of the η
3
-coordination mode was determined by NMR spectroscopy and X-ray structure analysis on a single crystal. |
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| ISSN: | 1144-0546 1369-9261 |
| DOI: | 10.1039/D3NJ04406H |